Asked by Camila Salazar on Jul 31, 2024

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Which of the following statements is the best statement of the Hammond Postulate?

A) In an endothermic reaction, the transition state is closer to the reactants in structure.
B) In an exothermic reaction, the transition state is closer in energy to the products.
C) Related species that are similar in energy are also similar in structure.
D) The structure of the transition state in an organic reaction is always modeled on the structure of the reactants leading to that transition state.
E) Transition states are molecular species of finite lifetime whose properties can be probed through free radical reactions.

Hammond Postulate

The Hammond postulate suggests that the transition state of a reaction resembles the structure of the closest stable species on the reaction path, either the products or the reactants.

Transition State

The highest-energy state during a chemical reaction where the reactants are transformed into products, representing the point of highest energy on a reaction coordinate.

Endothermic Reaction

A chemical reaction that absorbs heat from its surroundings.

  • Understand the Hammond Postulate and its application in predicting reaction pathways and transition states.
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ZK
Zybrea KnightAug 04, 2024
Final Answer :
C
Explanation :
The Hammond Postulate states that related species that are similar in energy are also similar in structure, which is best reflected in option C.