Asked by Kyara Negra on Apr 24, 2024

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Which compound would be expected to show intense IR absorption at 1746 cm-1?

A) CH3CH2OCH2CH3
B) CH3CH2CN
C) CH3CO2CH2CH3
D) CH3CH2SCH3

Intense IR Absorption

A characteristic of some materials to strongly absorb infrared radiation at specific wavelengths, indicative of particular molecular bonds.

  • Study the IR absorption phenomena in chemical bonds and functional groups.
  • Absorb the principles relating molecular structure to IR spectral variations.
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ZK
Zybrea KnightMay 02, 2024
Final Answer :
C
Explanation :
The intense IR absorption at 1746 cm-1 is characteristic of the carbonyl group (C=O). Choice A and D both contain a carbonyl group, but they also have other functional groups that can absorb IR radiation, so they would not exhibit an intense absorption solely at 1746 cm-1. Choice B contains a nitrile group (C≡N), which has an IR absorption peak around 2200 cm-1, not 1746 cm-1. Only choice C contains a single carbonyl group and no other functional groups that would interfere with its IR absorption in that region, making it the best choice.