Asked by Brian Lynch on Jun 20, 2024

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Which base, ammonia (NH3) or triethylamine [(CH3CH2)3N], would be a better choice for use in converting 1-chlorohexane to hex-1-ene? Explain briefly.

Ammonia

A compound of nitrogen and hydrogen with the formula NH3, known for its pungent smell and use as a nitrogen source in fertilizers.

Triethylamine

A strong, organic base with the formula (C2H5)3N, used as a catalyst and solvent in chemical synthesis.

  • Recognize the role of bases in elimination reactions.
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JL
Jacob LandryJun 24, 2024
Final Answer :
Triethylamine. Amines can serve as both nucleophiles and as bases in reactions with alkyl halides. Increasing the steric bulk about the nitrogen diminishes the nucleophilicity while allowing the amine to continue to function effectively as a base.