Asked by Nurul Ainaa on Jul 31, 2024

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Glucose has a specific rotation of +52.8°. Predict the concentration of a glucose aqueous solution contained in a 10 cm long polarimetry tube if a rotation of +15.8° was observed.

A) 0.299 g/mL
B) 0299 g/mL
C) 3.34 g/mL
D) 334 g/mL

Polarimetry Tube

A laboratory device used to measure the rotation of polarized light as it passes through optically active substances.

Specific Rotation

A physical property of chiral compounds, describing the direction and magnitude of rotation of plane-polarized light by a substance.

Glucose

A simple sugar and important energy source in living organisms, classified as a monosaccharide and playing a crucial role in carbohydrate metabolism.

  • Estimate the implications of compound concentration adjustments and solution conditions on the measurements of specific rotation.
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DH
dbzMASTER HUGHESAug 04, 2024
Final Answer :
A
Explanation :
The specific rotation [α][\alpha][α] of a substance is related to the observed rotation α\alphaα , the concentration ccc in grams per milliliter (g/mL), and the path length lll in decimeters (dm) by the formula [α]=αl⋅c[\alpha] = \frac{\alpha}{l \cdot c}[α]=lcα . Given [α]=+52.8°[\alpha] = +52.8°[α]=+52.8° , α=+15.8°\alpha = +15.8°α=+15.8° , and l=10cm=1dml = 10 cm = 1 dml=10cm=1dm , we can solve for ccc : c=α[α]⋅l=15.852.8⋅1=0.299g/mLc = \frac{\alpha}{[\alpha] \cdot l} = \frac{15.8}{52.8 \cdot 1} = 0.299 g/mLc=[α]lα=52.8115.8=0.299g/mL .