Asked by Kristýna Vošická on May 25, 2024

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A three-carbon, nitrogen-containing compound exhibits 3 13C NMR peaks (d 11.2, 27.3, and 44.9) . Which of the following compounds best matches this spectral data?

A) H2NCH2CH2CH2OH
B) (CH3) 2CHNH2
C) CH3NHCH2CH3
D) CH3CH2CH2NH2
E) CH3CH2C≡N

NMR Peaks

The visible peaks in a nuclear magnetic resonance spectrum, each corresponding to a different chemical environment of nuclei in a molecule.

Nitrogen-Containing

Refers to molecules or moieties that include one or more nitrogen atoms within their structure.

Spectral Data

Information obtained from the analysis of the spectrum of a compound, which can reveal properties such as structure and composition.

  • Leverage IR, NMR, and mass spectroscopy methods to identify and characterizes various types of amines.
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OO
Oluwapelumi OlanrewajuMay 31, 2024
Final Answer :
D
Explanation :
The NMR peaks indicate that there are three different types of carbon environments in the molecule. The peak at d 44.9 indicates the presence of a carbon next to a nitrogen atom, which is consistent with the structure of choice D. The other peaks at d 27.3 and 11.2 are likely due to different types of carbon-hydrogen environments in the molecule. Choices A, B, C, and E do not have a nitrogen-bound carbon or have more than three carbons.